Refining dross is the
result of lead refining process where impurities like copper,
tellurium, arsenic-antimony-tin, silver, zinc and bismuth in sequence from lead
bullion. Composition of each type of dross varies and is subjected to specific
refining steps and raw material contents. Conversely, lead refining process are
taken in account for the convenience of refining dross recovery.
Generally
speaking, the copper dross is treated by reveberatory furnace. In case of
copper dross with high arsenic, tin and antimony, caustic soda plus iron
filings are used. In reaction with caustic soda, the arsenic, tin and antimony
report to sodium salt as slag to be recovered by hydrometallurgy consequently. After
soda refining, the copper matte is treated by cupellation method to separate
copper with lead, and lead reports into slag phase. Complete separation of Te,
As, Sn and Sb is accomplished by chemical methods in a leaching plant.
Apart
from conventional dross treatment methods, Metalcess focuses on treating tin slag
from Harris refining process, silver-zinc crust/silver foam from Parkes process
and lead anode slime treatment. With Metalcess solution, high purity tin is
obtained by combining fire-refining and vacuum distillation.
Metalcess
provides an integrated system combining liquation and distillation technology
to treat silver-zinc crust/silver foam from Parkes process, in which zinc, lead
and silver are separated efficiently at the cost of low energy consumption.
Noticeably, the zinc recovered from silver-zinc crust can be used as
desilvering agent again for the Parkes process. While the lead alloy can be
charged to lead refining pot before bismuth-removing step. This system is
superior in reducing energy consumption, shortening process flow and improving
working environment.